![]() Now that we’ve calculated the number of valence electrons available to us, we move on towards building up the Lewis structure for SO 2. Thus, the total number of valence electrons available to form is given by:Ħ + 12 = 18 valence electrons. Therefore, the two Oxygen atoms present contribute 6 x 2 = 12 valence electrons. Oxygen’s electronic configuration is 1s 2 2s 2 2p 4. Oxygen has six valence electrons (group 6) and has a valency of -2. ![]() ![]() Therefore, the Sulfur atom contributes 6 x 1 = 6 valence electrons Sulfur is in group 6(Chalcogens) of the periodic table with the electronic configuration 3s☣p⁴. There are two oxygen atoms and one sulfur atom present in SO 2. As such, they can potentially break free to take part in bond formation and exchanges.Įach constituent atom in the compound contributes a set amount of valence electrons to the overall structure. They are found in the atom’s outermost shell, where the force of attraction from the nucleus is the weakest. These valence electrons act as the building blocks of the structure. To form the Lewis structure of Sulfur Dioxide, we need first to determine the number of valence electrons available. SO2 Molecular Geometry and Shape SO 2 Valence Electrons.of valence electrons 6 + (6 x 2) = 18 valence electrons Hybridization of the central atom sp 2 Bond Angles 119 ° Molecular Geometry of SO 2 Bent Molecular Geometry SO 2 has the following properties: Name of the compound Sulfur Dioxide (SO 2 ) No. Prolonged exposure can lead to respiratory illnesses. It is also being looked at as a potential refrigerant and as a tool for climate engineering.Īs an irritant, it must be handled with care. In addition to its wide industrial use, SO 2 is also used as a preservative in dried fruits, a reagent in the laboratory, and various biomedical applications. Billions of kilograms of SO 2 are produced annually to meet global requirements. A combination of Oleum with water gives Sulfuric Acid. Here, SO 2 is converted to Sulfur Trioxide, which combines with sulfuric acid to give Oleum (disulfuric acid). ![]() The gas released is captured and primarily used in the production of Sulfuric Acid through the contact process. Sulfur Dioxide is manufactured on an industrial scale by burning or roasting Sulfur and its components (Sulfide ores, Sulfites) in the presence of Oxygen. Trace amounts of the compound have also been observed on other bodies in the solar system. This is evidenced by the sulfur cycle observed on Venus, where it forms clouds of Sulfuric acid. Sulfur Dioxide contributes to global warming as a proponent of the greenhouse effect. It is also found in some hot water springs. The substance is a colorless gas with a recognizable pungent odor similar to the smell of a burnt matchstick.Ī large quantity of SO 2 is released during volcanic eruptions. But it is related to dipole moment and assertion is the explanation from bent angle so here reason is unable to give explanation of assertion.The chemical formula SO 2 represents the chemical compound Sulfur Dioxide. S atom in both S O 2 and S O 3 is sp2 -hybridized. The extra repulsion of the lp vs double bonds accounts for reduction to 119. In S O 2, we have 2 double bonds and one lone pair 3 electron regions so the default angle is 120 degrees. The S O 2 molecule has a dipole moment, The starting point of 109.5 degrees is only applicable for 4 electron regions round the central atom. The bonding in S O 3 can be described as a combination of 3 resonance forms of 1 double and 2 single bonds. So the shape is based on a tetrahedral structure - but the extra repulsion of the non-bonding pair will decrease the O-S-O angles by a few degrees from the 'perfect' tetrahedral angle. There are 3 bonding sets of electrons and one non-bonding pair on the sulphur. The correct option is B If both assertion and reason are CORRECT, but reason is NOT THE CORRECT explanation of the assertion.
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